芳基高价碘盐诱导的亲电环化反应研究
摘要
亲电试剂诱导的环化反应是构建环状化合物的有效策略, 而利用芳基高价碘盐作为亲电试剂诱导环化反应已经取得了诸多研究进展. 在这些亲电环化反应中, 高价碘盐不仅可以作为芳基化试剂诱导环化反应形成芳基取代环化物, 还可以诱导苯并环化反应, 形成苯并环状化合物.
关键词 ： 芳基高价碘, 亲电环化, 芳化-环化反应, 苯并环化反应
Abstract：
Electrophilic cyclization reactions are one of the most useful strategies for the construction of various cyclic compounds and significant progress has been made in the electrophilic cyclizations triggered by diaryliodonium salts. In these new types of electrophilic cyclization reactions, diaryliodonium salts can not only act as arylation reagents to initiate arylation-cyclization reactions giving aryl-substituted compounds, but also to be involved in the benzocyclization to give benzocycles.
陈静, 曲红梅, 彭静, 陈超. 芳基高价碘盐诱导的亲电环化反应研究[J]. 有机化学, 2015, 35(5): 937-946
