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Lawesson's reagent, or LR, is a chemical compound used in organic synthesis as a thiation agent. Lawesson's reagent was first made popular by Sven-Olov Lawesson, who did not, however, invent it. Lawesson's reagent was first made in 1956 during a systematic study of the reactions of arenes with P4S10
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Lawesson's reagent相关参考文献:
Lecher, H. Z.; Greenwood, R. A.; Whitehouse, K. C.; Chao, T. H. (1956). "The Phosphonation of Aromatic Compounds with Phosphorus Pentasulfide". J. Am. Chem. Soc. 78: 5018. doi:10.1021/ja01600a058.
Thomsen, I.; Clausen, K.; Scheibye, S.; Lawesson, S.-O. (1990). "Thiation with 2,4-Bis(4-methoxyphenyl)-1,3,2,4-Dithiadiphosphetane 2,4-disulfide: N-Methylthiopyrrolidone". Org. Synth.; Coll. Vol. 7: 372.
Cherkasov, R. A.; Kutyrev, G. A.; Pudovik, A. N. (1985). "Tetrahedron report number 186 Organothiophosphorus reagents in organic synthesis" (Review). Tetrahedron 41 (41): 2567. doi:10.1016/S0040-4020(01)96363-X.
Foreman, M.S.; Woollins, J.D. (2000). "Organo-P-S and P-Se heterocycles". J. Chem. Soc., Dalton Trans.: 1533–1543. doi:10.1039/b000620n.
Martin Jesberger, Thomas P. Davis, Leonie Barner (2003). "Applications of Lawesson’s Reagent in Organic and Organometallic Syntheses" (Review). Synthesis 2003: 1929–1958. doi:10.1055/s-2003-41447.
Cava, M. P.; Levinson, M. I. (1985). "Thionation reactions of Lawesson's reagents". Tetrahedron 41 (22): 5061–5087. doi:10.1016/S0040-4020(01)96753-5.
Pedersen, B. S.; Scheibye, S.; Nilsson, N. H.; Lawesson, S.-O. (1978). "{{{title}}}". Bull. Soc. Chim. Belg. (87): 223.
Jones, B. A.; Bradshaw, J. S. (1984). "Synthesis and reduction of thiocarboxylic O-esters" (Review). Chem. Rev. 84 (84): 17. doi:10.1021/cr00059a002.
Scheibye, S.; Kristensen, J.; Lawesson, S.-O. (1979). "Studies on organophosphorus compounds—XXVII Synthesis of thiono-, thiolo- and dithiolactones". Tetrahedron 35 (35): 1339. doi:10.1016/0040-4020(79)85027-9.
Shabana, R.; Scheibye, S.; Clausen, K.; Olesen, S. O.; Lawesson, S.-O. (1980). "{{{title}}}". Nouv. J. Chim. (4): 47.
Daniel Brayton, Faith E. Jacobsen, Seth M. Cohen and Patrick J. Farmer (2006). "A novel heterocyclic atom exchange reaction with Lawesson's reagent: a one-pot synthesis of dithiomaltol". Chemical Communications 2006: 206–208. doi:10.1039/b511966a.
